Issue 17, 2016
From the journal:

Dalton Transactions

Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine†

Tomoaki Tanase,*a   Kanako Koike,a   Miho Uegaki,a   Satoko Hatada,a   Kanako Nakamae,a   Bunsho Kure,a   Yasuyuki Uraa  and  Takayuki Nakajima*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-nishi-machi, Nara 630-8506, Japan
E-mail: tanase@cc.nara-wu.ac.jp
Fax: +81-742-20-3847

Abstract

Linear triplatinum complexes with 48e−, [Pt3(μ-tdpmp)2(RNC)2](PF6)2 (R = 2,6-xylyl (3), tBu (4)), were synthesized by using a branched tetraphosphine, tris(diphenylphosphinomethyl)phosphine (tdpmp), and characterized by crystallographic and spectroscopic analyses to show their novel dynamic behaviour in the solution state, in which the linear Pt3 unit was stabilized by two spinning tetraphosphine ligands.

Graphical abstract: Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine

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Article information

DOI
https://doi.org/10.1039/C6DT00624H
Article type
Communication
Submitted
16 Feb 2016
Accepted
29 Mar 2016
First published
07 Apr 2016

Dalton Trans., 2016,45, 7209-7214

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Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine

T. Tanase, K. Koike, M. Uegaki, S. Hatada, K. Nakamae, B. Kure, Y. Ura and T. Nakajima, Dalton Trans., 2016, 45, 7209 DOI: 10.1039/C6DT00624H

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