Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

Lei-Lei Li; Rui Pan; Jun-Wei Zhao; Bai-Feng Yang; Guo-Yu Yang

doi:10.1039/C6DT01909A

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Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)†

Lei-Lei Li,^a Rui Pan,^a Jun-Wei Zhao,^c Bai-Feng Yang^a and Guo-Yu Yang*^ab

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
E-mail: ygy@bit.edu.cn

^b Department of Chemistry, Key Laboratory for preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, Guangdong 515063, China

^c Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

Abstract

Two organic–inorganic hybrid pillared-layer lanthanide borates, [Ln₂B₈O₁₂(bdc)₃(H₂O)]·H₂O (Ln = Pr, 1; Nd, 2; H₂bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B₁₂O₂₈/Ln@B₁₂O₂₉, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln–O–C and B–O–C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

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Article information

DOI: https://doi.org/10.1039/C6DT01909A
Article type: Communication
Submitted: 14 May 2016
Accepted: 10 Jun 2016
First published: 13 Jun 2016

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Dalton Trans., 2016,45, 11628-11632

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Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

L. Li, R. Pan, J. Zhao, B. Yang and G. Yang, Dalton Trans., 2016, 45, 11628 DOI: 10.1039/C6DT01909A

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