A closer look on the coordination of soft nitrogen-donor ligands to Cm(III): SO3-Ph-BTBP

M. Trumm; C. Wagner; B. Schimmelpfennig; A. Geist; P. J. Panak

doi:10.1039/C6DT02052F

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A closer look on the coordination of soft nitrogen-donor ligands to Cm(iii): SO₃-Ph-BTBP

M. Trumm,*^a C. Wagner,*^ab B. Schimmelpfennig,^a A. Geist^a and P. J. Panak^ab

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* Corresponding authors

^a Institut für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie, D-76131 Karlsruhe, Germany
E-mail: Michael.Trumm@kit.edu

^b Ruprecht Karls Universität Heidelberg, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 253, D-69120 Heidelberg, Germany
E-mail: Christoph.Wagner@kit.edu

Abstract

We present a combined theoretical and experimental study on the recently developed hydrophilic SO₃-Ph-BTBP ligand. Vibronic side band spectroscopy and time-resolved laser fluorescence spectroscopy (TRLFS) were employed to prove the theoretical prediction of the ligand's coordination mode.

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Article information

DOI: https://doi.org/10.1039/C6DT02052F
Article type: Communication
Submitted: 23 May 2016
Accepted: 15 Jul 2016
First published: 15 Jul 2016

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Dalton Trans., 2016,45, 12308-12311

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A closer look on the coordination of soft nitrogen-donor ligands to Cm(III): SO₃-Ph-BTBP

M. Trumm, C. Wagner, B. Schimmelpfennig, A. Geist and P. J. Panak, Dalton Trans., 2016, 45, 12308 DOI: 10.1039/C6DT02052F

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Dalton Transactions