Issue 42, 2016
From the journal:

Dalton Transactions

Water-dependent charge-transfer-induced spin transition of Prussian blue analogues†

Hitomi Ohmagari,a   Ryo Ohtani,a   Manabu Nakaya,a   Masaaki Ohba,b   Masaaki Nakamura,a   Leonard F. Lindoy,c   Osamu Satod  and  Shinya Hayami*ae  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan
E-mail: hayami@sci.kumamoto-u.ac.jp

b Department of Chemistry, Faculty of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

c School of Chemistry, the University of Sydney, NSW 2006, Australia

d Institute for Material Chemistry and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

e Institute of Pulsed Power Science (IPPS), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

Abstract

Cobalt–iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.

Graphical abstract: Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

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Article information

DOI
https://doi.org/10.1039/C6DT03474H
Article type
Communication
Submitted
06 Sep 2016
Accepted
29 Sep 2016
First published
30 Sep 2016

Dalton Trans., 2016,45, 16784-16788

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Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

H. Ohmagari, R. Ohtani, M. Nakaya, M. Ohba, M. Nakamura, L. F. Lindoy, O. Sato and S. Hayami, Dalton Trans., 2016, 45, 16784 DOI: 10.1039/C6DT03474H

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