Issue 4, 2016
From the journal:

Green Chemistry

A photoactive bimetallic framework for direct aminoformylation of nitroarenes†

R. B. Nasir Baig,‡a   Sanny Verma,‡a   Mallikarjuna N. Nadagoudab  and  Rajender S. Varma*a  

* Corresponding authors

a Sustainable Technology Division, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, USA
E-mail: varma.rajender@epa.gov
Fax: +1 513-569-7677
Tel: +1 513-487-2701

b WQMB, WSWRD, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, MS 443, Cincinnati, Ohio 45268, USA

Abstract

A bimetallic catalyst, AgPd@g-C3N4, synthesized by reducing silver and palladium salts over graphitic carbon nitride (g-C3N4), enables the concerted reductive formylation of aromatic nitro compounds under photo-chemical conditions using formic acid, which serves the dual role of a hydrogen source and a formylating agent.

Graphical abstract: A photoactive bimetallic framework for direct aminoformylation of nitroarenes

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Article information

DOI
https://doi.org/10.1039/C5GC02799C
Article type
Paper
Submitted
20 Nov 2015
Accepted
14 Dec 2015
First published
15 Dec 2015

Green Chem., 2016,18, 1019-1022

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A photoactive bimetallic framework for direct aminoformylation of nitroarenes

R. B. Nasir Baig, S. Verma, M. N. Nadagouda and R. S. Varma, Green Chem., 2016, 18, 1019 DOI: 10.1039/C5GC02799C

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