Pd-indenyl-diphosphine: an effective catalyst for the preparation of triarylamines

Meng-Qi Yan; Jia Yuan; Yun-Xiao Pi; Jin-Hua Liang; Yan Liu; Qing-Guo Wu; Xue Luo; Sheng-Hua Liu; Jian Chen; Xiao-Lei Zhu; Guang-Ao Yu

doi:10.1039/C5OB01934F

Pd-indenyl-diphosphine: an effective catalyst for the preparation of triarylamines†

Meng-Qi Yan,^a Jia Yuan,^b Yun-Xiao Pi,^a Jin-Hua Liang,^a Yan Liu,^c Qing-Guo Wu,^a Xue Luo,^a Sheng-Hua Liu,^a Jian Chen,^a Xiao-Lei Zhu*^a and Guang-Ao Yu*^a

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* Corresponding authors

^a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Central China Normal University, Wuhan 430079, China
E-mail: yuguang@mail.ccnu.edu.cn

^b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

^c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Abstract

A new Buchwald-type diphosphine ligand has been developed for applications in Pd-catalyzed amination reactions towards the preparation of triarylamines. The catalyst can be used to perform the amination of a diverse array of aryl and heteroaryl chlorides.

Organic & Biomolecular Chemistry

Pd-indenyl-diphosphine: an effective catalyst for the preparation of triarylamines†

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