An unprecedented method for the synthesis of β-alkoxy sulfides via a NaI/HBr-mediated three-component oxysulfenylation reaction of alkenes with arylsulfinic acids and alcohols is reported. Furthermore, I2-promoted oxysulfenylation of alkenes using sodium arylsulfinates instead of arylsulfinic acids to synthesise various β-alkoxy sulfides is also described.
D. Wang, R. Zhang, W. Ning, Z. Yan and S. Lin, Org. Biomol. Chem., 2016, 14, 5136 DOI: 10.1039/C6OB00646A
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