Carbamate-tethered propargyl and benzocyclononyne moieties within a single molecular unit undergo cycloaddition with azides under complementary CuAAC and/or SPAAC coupling conditions. The carbamate linker can be cleaved by analogy to the –CBz protecting group for click capture-and-release applications.
R. R. Ramsubhag and G. B. Dudley, Org. Biomol. Chem., 2016, 14, 5028 DOI: 10.1039/C6OB00795C
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