Issue 31, 2016
From the journal:

Organic & Biomolecular Chemistry

ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide†

Ryota Yoshida, ORCID logo ab   Katsuhiro Isozaki,*ab   Tomoya Yokoi,ab   Nobuhiro Yasuda,c   Koichiro Sadakane,d   Takahiro Iwamoto,ae   Hikaru Takaya*ab  and  Masaharu Nakamura*ab  

* Corresponding authors

a International Research Center for Elements Science, Institute for Chemical Research, Kyoto University, Uji, Kyoto, Japan
E-mail: takaya@scl.kyoto-u.ac.jp, masaharu@scl.kyoto-u.ac.jp

b Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, Japan

c JASRI, SPring-8, 1-1-1, Kouto, Sayo Hyogo, Japan

d Department of Biomedical Information, Faculty of Life and Medical Sciences, Doshisha University, 1-3 Tatara Miyakotani, Kyotanabe, Kyoto, Japan

e CREST, The Japan Science and Technology Agency (JST), Japan

Abstract

The enhanced catalytic activity of ruthenium complex-bound norvaline Boc-L-[Ru]Nva-OMe 1, in which the ONO-pincer ruthenium complex Ru(pydc)(terpy) 2 is tethered to the α-side chain of norvaline, has been demonstrated for the oxidation of methoxybenzenes to p-benzoquinones with a wide scope of substrates and unique chemoselectivity.

Graphical abstract: ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/C6OB00969G
Article type
Paper
Submitted
04 May 2016
Accepted
08 Jun 2016
First published
08 Jun 2016

Org. Biomol. Chem., 2016,14, 7468-7479

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ONO-pincer ruthenium complex-bound norvaline for efficient catalytic oxidation of methoxybenzenes with hydrogen peroxide

R. Yoshida, K. Isozaki, T. Yokoi, N. Yasuda, K. Sadakane, T. Iwamoto, H. Takaya and M. Nakamura, Org. Biomol. Chem., 2016, 14, 7468 DOI: 10.1039/C6OB00969G

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