Issue 30, 2016

Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives

Abstract

Enantioselective introduction of the functionalized monofluorinated methylenes into the allylic fragment under Ir catalysis has been realized, which gave the fluorinated branched allyl products in good to high yields with excellent regio- and enantioselectivities.

Graphical abstract: Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2016
Accepted
30 Jun 2016
First published
30 Jun 2016

Org. Biomol. Chem., 2016,14, 7183-7186

Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives

H. Zhang, J. Chen and X. Zhao, Org. Biomol. Chem., 2016, 14, 7183 DOI: 10.1039/C6OB01246A

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