Synthesis of esters via sp3 C–H functionalisation

Abstract

Oxidative C–O bond formation via sp³ C–H functionalisation represents an attractive approach for the synthesis of esters. This review focuses on the recent advances of sp³ C–H bond functionalisation strategies for ester synthesis from unconventional precursors using transition metal/metal free catalysts in combination with various oxidants. Various classes of esters and the mechanisms of their formation are discussed with numerous examples.