Despite its distance from the active site the flexible amino-terminal segment (NTS) in the β-domain of the plant sesquiterpene cyclase δ-cadinene synthase (DCS) is essential for active site closure and desolvation events during catalysis.
V. González, D. J. Grundy, J. A. Faraldos and R. K. Allemann, Org. Biomol. Chem., 2016, 14, 7451 DOI: 10.1039/C6OB01398H
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