Irradiation of quaternary ammonium salts of phenylglyoxylic acid used as photobase generators activates the release of a strong base in water followed by an important pH jump. This initiates the polymerization of dopamine, leading to an on-demand formation of highly adhesive coating on steel.
D. Perrot, C. Croutxé-Barghorn and X. Allonas, Polym. Chem., 2016, 7, 2635 DOI: 10.1039/C6PY00356G
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