Issue 6, 2016
From the journal:

Inorganic Chemistry Frontiers

Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium†

Xu Liu,a   Zikuan Wang,a   Xianyuan Zhaoa  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn

Abstract

Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed. Mechanistic studies reveal that the rhodium aryl complex, (por)Rh-C6F4R, is the key intermediate.

Graphical abstract: Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

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Article information

DOI
https://doi.org/10.1039/C5QI00269A
Article type
Research Article
Submitted
01 Dec 2015
Accepted
31 Mar 2016
First published
05 Apr 2016

Inorg. Chem. Front., 2016,3, 861-865

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Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

X. Liu, Z. Wang, X. Zhao and X. Fu, Inorg. Chem. Front., 2016, 3, 861 DOI: 10.1039/C5QI00269A

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