Issue 8, 2016
From the journal:

Inorganic Chemistry Frontiers

Understanding the magnetism of {Fe2Ln} dimers, step-by-step†

S. G. Baca,ab   J. van Leusen,b   M. Speldrichb  and  P. Kögerler ORCID logo *bc  

* Corresponding authors

a Institute of Applied Physics, Academy of Sciences of Moldova, 5 Academiei str., Chisinau, MD-2028, Moldova

b Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

c Peter Grünberg Institute, PGI-6, Research Centre Jülich, D-52425 Jülich, Germany

Abstract

A magnetochemical comparison between the {FeIII4LnIII2}-type coordination clusters [Fe4M2(OH)2(N3)2(bdea)4(O2CCMe3)5(H2O)]NO3·2(EtOH) (M = Dy, Y) and [Fe4M2(OH)2(N3)2(bdea)4(O2CCMe3)4(NO3)2]·3(EtOH) (M = Gd, Eu; H2bdea = N-butyldiethanolamine), of which {Fe4Dy2} reveals slow molecular magnetization relaxation up to 6 K, allows assessment of the exchange coupling governing the clusters’ multiplet patterns.

Graphical abstract: Understanding the magnetism of {Fe2Ln} dimers, step-by-step

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Article information

DOI
https://doi.org/10.1039/C6QI00095A
Article type
Research Article
Submitted
15 Apr 2016
Accepted
13 Jun 2016
First published
13 Jun 2016
This article is Open Access
Creative Commons BY-NC license

Inorg. Chem. Front., 2016,3, 1071-1075

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Understanding the magnetism of {Fe2Ln} dimers, step-by-step

S. G. Baca, J. van Leusen, M. Speldrich and P. Kögerler, Inorg. Chem. Front., 2016, 3, 1071 DOI: 10.1039/C6QI00095A

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