Issue 9, 2016
From the journal:

Organic Chemistry Frontiers

An easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi as a CO surrogate under mild conditions†

Yang Wang,a   Yongming Zeng,a   Bangyu Yanga  and  Yian Shi*abc  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: yian.shi@colostate.edu

b Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

c Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA

Abstract

This paper describes an easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi and Ac2O under mild conditions without using external CO gas.

Graphical abstract: An easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi as a CO surrogate under mild conditions

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Article information

DOI
https://doi.org/10.1039/C6QO00187D
Article type
Research Article
Submitted
07 May 2016
Accepted
16 Jul 2016
First published
18 Jul 2016

Org. Chem. Front., 2016,3, 1131-1136

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An easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi as a CO surrogate under mild conditions

Y. Wang, Y. Zeng, B. Yang and Y. Shi, Org. Chem. Front., 2016, 3, 1131 DOI: 10.1039/C6QO00187D

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