Issue 17, 2016

[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(i) phosphinine complexes

Abstract

Two novel rhenium(I) phosphinine complexes [Re(CO)3Cl(η1-C5H4ClP)2] (1) and [Re(CO)2Cl(η1-C5H4ClP)3] (2) were synthesized and the molecular structure of both was determined by single crystal X-ray diffraction. In compound 1 the two coordinated phosphinine ligands are arranged in a cis position, whereas compound 2 with three phosphinine ligands crystallizes in a meridional structural motif. Density functional theory investigations were executed to examine the relative stabilities of both complexes 1 and 2.

Graphical abstract: [Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(i) phosphinine complexes

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2015
Accepted
25 Jan 2016
First published
27 Jan 2016
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2016,6, 14134-14139

[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(I) phosphinine complexes

M. Hollering, R. O. Reithmeier, S. Meister, E. Herdtweck, F. E. Kühn and B. Rieger, RSC Adv., 2016, 6, 14134 DOI: 10.1039/C5RA25904E

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