Issue 26, 2016

The environmental impact of unsaturated fluoroesters: atmospheric chemistry towards OH radicals and Cl atoms, radiative behavior and cumulative ozone creation

Abstract

Smog chamber/GC techniques were used to investigate the atmospheric degradation of two hydrofluoroesters (allyl trifluoroacetate (CF3C(O)OCH2CH[double bond, length as m-dash]CH2) and vinyl trifluoroacetate (CF3C(O)OCH[double bond, length as m-dash]CH2)) by oxidation with OH radicals and Cl atoms at 298 K and an atmospheric pressure of N2 or air. The measured rate coefficients were (in units of cm3 per molecule per s): kallyl trifluoroacetate+OH = (9.27 ± 3.81) × 10−12; kvinyl trifluoroacetate+OH = (8.07 ± 1.92) × 10−12; kallyl trifluoroacetate+Cl = (1.75 ± 0.21) × 10−10 and kvinyl trifluoroacetate+Cl = (2.08 ± 0.16) × 10−10. In the OH-initiated oxidation of allyl trifluoroacetate, the identified product can arise from OH addition to both carbons in the double bond and the later decomposition of the alkoxy radical formed. However, in the reactions of both fluoroesters with Cl atoms, the main product detected arises from Cl addition to the terminal carbon atom and the subsequent reaction of the chloroalkoxy radical formed with O2. Infrared spectra of the studied esters were collected and their contribution to global warming was assessed by calculating their radiative efficiencies. Combining these results with the kinetic data we found that their global warming potentials are negligible. Finally, the photochemical ozone creation potentials were calculated, obtaining values lower than those of non-fluorinated unsaturated hydrocarbons.

Graphical abstract: The environmental impact of unsaturated fluoroesters: atmospheric chemistry towards OH radicals and Cl atoms, radiative behavior and cumulative ozone creation

Supplementary files

Article information

Article type
Paper
Submitted
08 Jan 2016
Accepted
16 Feb 2016
First published
17 Feb 2016

RSC Adv., 2016,6, 21833-21843

The environmental impact of unsaturated fluoroesters: atmospheric chemistry towards OH radicals and Cl atoms, radiative behavior and cumulative ozone creation

A. Rodríguez, I. Bravo, D. Rodríguez, M. Tajuelo, Y. Diaz-de-Mera and A. Aranda, RSC Adv., 2016, 6, 21833 DOI: 10.1039/C6RA00630B

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