Issue 20, 2016
From the journal:

RSC Advances

A new application of the traditional Fenton process to gold cyanide synthesis using acetonitrile as a cyanide source†

Wuzhong Yi,a   Xiaoqing Yan,b   Renhong Li,*ab   Jian-Qiang Wang,c   Shihui Zou,a   Liping Xiao,a   Hisayoshi Kobayashid  and  Jie Fan*a  

* Corresponding authors

a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310027, China
E-mail: jfan@zju.edu.cn

b Key Lab of Advanced Textile Materials and Manufacturing Technology, Ministry of Education of China, Zhejiang Sci-Tech University, Hangzhou 310018, China
E-mail: lirenhong@zju.edu.cn

c Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China

d Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto, Japan

Abstract

Previous cyanation processes always involved the use of hypertoxic CN− ions or UV-light, which is health-risky and energy-wasting. For the purpose of environment-friendly chemistry, we introduced a general Fenton-reaction synthesis of metal cyanide solids using acetonitrile as a green cyanide source. This Fenton-improved cyanation method gets rid of CN− ions and UV-light efficiently, which is green and facile.

Graphical abstract: A new application of the traditional Fenton process to gold cyanide synthesis using acetonitrile as a cyanide source

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Article information

DOI
https://doi.org/10.1039/C6RA01025C
Article type
Communication
Submitted
13 Jan 2016
Accepted
26 Jan 2016
First published
28 Jan 2016

RSC Adv., 2016,6, 16448-16451

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A new application of the traditional Fenton process to gold cyanide synthesis using acetonitrile as a cyanide source

W. Yi, X. Yan, R. Li, J. Wang, S. Zou, L. Xiao, H. Kobayashi and J. Fan, RSC Adv., 2016, 6, 16448 DOI: 10.1039/C6RA01025C

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