Issue 31, 2016
From the journal:

RSC Advances

Zn(ii) porphyrin based nano-/microscale metal–organic frameworks: morphology dependent sensitization and photocatalytic oxathiolane deprotection†

Fang-Yao Zhao,a   Wen-Juan Li,a   An Guo,a   Lan Chang,a   Yue Li*a  and  Wen-Juan Ruan*a  

* Corresponding authors

a Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
E-mail: wjruan@nankai.edu.cn, liyue84@nankai.edu.cn
Tel: +86-22-23501717

Abstract

With Zn(II) porphyrin as a building block, nano-/microscale MOFs with different morphologies were synthesized as sensitizers for O2 (forming 1O2). The sensitization efficiency was observed to enhance remarkably with the decrease of morphological dimension of the sample. With high sensitization ability, the one-dimensional MOF could selectively photocatalyze the deprotection of oxathiolanes to ketones.

Graphical abstract: Zn(ii) porphyrin based nano-/microscale metal–organic frameworks: morphology dependent sensitization and photocatalytic oxathiolane deprotection

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6RA01599A
Article type
Communication
Submitted
19 Jan 2016
Accepted
29 Feb 2016
First published
02 Mar 2016

RSC Adv., 2016,6, 26199-26202

Permissions

Request permissions

Zn(II) porphyrin based nano-/microscale metal–organic frameworks: morphology dependent sensitization and photocatalytic oxathiolane deprotection

F. Zhao, W. Li, A. Guo, L. Chang, Y. Li and W. Ruan, RSC Adv., 2016, 6, 26199 DOI: 10.1039/C6RA01599A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements