Issue 45, 2016, Issue in Progress
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RSC Advances

Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis†

Yuming Li,a   Huimin Liu,a   Lan Maab  and  Dehua He*a  

* Corresponding authors

a Innovative Catalysis Program, Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: hedeh@mail.tsinghua.edu.cn
Fax: +86-10-62773346
Tel: +86-10-62773346

b Institute of Chemical Defence, Beijing 102205, China

Abstract

Pd–Re/SBA-15 catalysts were prepared by the impregnation method. The influence of the interaction between Pd and Re in the Pd–Re catalysts on glycerol hydrogenolysis was investigated. Pd and Re had interaction which was confirmed by H2-TPR, XPS and EXAFS. In the Pd–Re catalysts, Re showed a higher oxidation state compared with that of the mono-component Re catalyst. The mechanically mixed Pd + Re catalysts showed a lower glycerol conversion than that of the bi-component Pd–Re catalysts, which suggested that the interaction of Pd and Re was very important in glycerol hydrogenolysis.

Graphical abstract: Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis

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Article information

DOI
https://doi.org/10.1039/C6RA02758J
Article type
Paper
Submitted
30 Jan 2016
Accepted
01 Apr 2016
First published
05 Apr 2016

RSC Adv., 2016,6, 38680-38689

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Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis

Y. Li, H. Liu, L. Ma and D. He, RSC Adv., 2016, 6, 38680 DOI: 10.1039/C6RA02758J

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