A FeCl3-catalyzed [3 + 2] cycloaddition reaction of aziridine with isothiocyanate was developed. The cycloaddition reaction was completed in two minutes with high chemoselectivity, stereoselectivity. 15 (tosylthiazolidin-2-ylidene)anilines were obtained with moderate to excellent yields.
![Graphical abstract: Quickly FeCl3-catalyzed highly chemo- and stereo-selective [3 + 2] dipolar cycloaddition of aziridines with isothiocyanates](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C6RA04923K&imageInfo.ImageIdentifier.Year=2016)
L. Gao, K. Fu and G. Zheng, RSC Adv., 2016, 6, 47192 DOI: 10.1039/C6RA04923K
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