Issue 61, 2016, Issue in Progress

MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

Abstract

We report palladium(II)-functionalized MOF-253 (MOF-253-Pd(OAc)2) as a recyclable catalyst to form all-carbon quaternary centers via conjugate additions of arylboronic acids to β,β-disubstituted enones in aqueous media. We demonstrate MOF-253-Pd(OAc)2 can be reused 8 times to form ketone products in yields above 75% while maintaining its crystallinity. Additions of a range of stereoelectronically diverse arylboronic acids to a variety of β,β-disubstituted enones catalyzed by MOF-253-Pd(OAc)2 occur in modest-to-high yields (34–95%).

Graphical abstract: MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

Supplementary files

Article information

Article type
Communication
Submitted
16 May 2016
Accepted
04 Jun 2016
First published
06 Jun 2016

RSC Adv., 2016,6, 56330-56334

Author version available

MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

R. Van Zeeland, X. Li, W. Huang and L. M. Stanley, RSC Adv., 2016, 6, 56330 DOI: 10.1039/C6RA12746K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements