Molecular weight effects of PEG on the crystal structure and photocatalytic activities of PEG-capped TiO2 nanoparticles

Abstract

Polyethylene glycol (PEG) was used as stabilizer to prepare water-soluble anatase titanium dioxide (TiO₂). The molecular weight effects of PEG on the crystal structure and photocatalytic activities of PEG-capped TiO₂ nanoparticles were systematically studied. The results show that the steric hindrance effect of PEG molecular chains will hinder the PEG molecules from being tied to the surface of TiO₂, resulting in the decrease of PEG molecules capped on the surface of TiO₂ with the growth of PEG molecular chains. It is significant that PEG can effectively promote the dispersion of TiO₂ nanoparticles in water, which becomes better and better with the increase of molecular weight of PEG. Moreover, the PEG-capped TiO₂ aqueous solutions can keep stable for more than two months. PEG cannot influence the crystal type and size of TiO₂, which can be well controlled by the introduction of HCl in the reaction system. The photocatalytic activity of PEG-capped TiO₂ was evaluated by monitoring the degradation of methyl orange, which is better than that of commercial P25 TiO₂ mainly due to the good dispersion in water. However, PEG molecular chains are detrimental to the transfer of photogenerated electrons and reactive oxygen species while the increasing dispersion in water with the increase of PEG molecular weight can increase the photocatalytic activity of TiO₂. As a result, PEG400 capped TiO₂ presents the best photocatalytic activity while PEG2000 capped TiO₂ exhibits the worst photocatalytic activity. The photocatalytic activity begins to increase when the molecular weight of PEG is larger than 2000.