Issue 87, 2016, Issue in Progress
From the journal:

RSC Advances

A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes†

Davir González-Calderón,*a   Marco A. Morales-Reza,a   Eduardo Díaz-Torres,a   Aydeé Fuentes-Benítesa  and  Carlos González-Romero*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón/Paseo Tollocan s/n, Toluca, Estado de México, Mexico
E-mail: cgonzalezr@uaemex.mx, qfb_dgonzalez@yahoo.com.mx

Abstract

The synthesis of carbonyl compounds from benzylic azides through benzylideneamides is described for the first time. NaH-mediated activation of benzyl azides allows a rapid water-promoted oxidation under a facile protocol with good yields.

Graphical abstract: A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

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Article information

DOI
https://doi.org/10.1039/C6RA13088G
Article type
Communication
Submitted
19 May 2016
Accepted
28 Aug 2016
First published
29 Aug 2016

RSC Adv., 2016,6, 83547-83550

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A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

D. González-Calderón, M. A. Morales-Reza, E. Díaz-Torres, A. Fuentes-Benítes and C. González-Romero, RSC Adv., 2016, 6, 83547 DOI: 10.1039/C6RA13088G

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