The carbonylative Suzuki–Miyaura reaction between aryl tosylates/triflates with arylboronic acid is herein reported, using base-free conditions and a balloon pressure of carbon monoxide. Under these conditions, unsymmetrical biaryl ketones were obtained in modest to excellent yields. This method was adapted to the synthesis of oxybenzone and ketoprofen in good yields under mild conditions.
C. Y. Hao, D. Wang, Y. W. Li, L. L. Dong, Y. Jin, X. R. Zhang, H. Y. Zhu and S. Chang, RSC Adv., 2016, 6, 86502 DOI: 10.1039/C6RA14678C
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