An efficient protocol for stereoselective synthesis of 2-arylvinylphosphonates has been developed via AgNO3-catalyzed cross-coupling of β-nitrostyrenes with dialkyl H-phosphites under mild conditions. By losing the nitro group of β-nitrostyrenes, the reaction proceeds smoothly and could provide the desired products with moderate to good yield.
J. Yuan, L. Yang, P. Mao and L. Qu, RSC Adv., 2016, 6, 87058 DOI: 10.1039/C6RA19002B
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