A review on Mn4+ activators in solids for warm white light-emitting diodes

Abstract

Currently, the major commercial white light-emitting diodes consist of a blue-emitting chip and Y₃Al₅O₁₂:Ce³⁺ yellow phosphor. However, the shortage of a red emitting component in the constructed device makes it difficult to realize warm white light with a high color-rendering index and low correlated color temperature. In this mini-review article, we provide an overview of recent progresses in developing Mn⁴⁺ doped red phosphors for promising applications in warm white light-emitting diodes. Firstly, the spectroscopic properties of Mn⁴⁺ in solids, including electronic and vibronic energy-level structures, crystal-field parameters as well as thermal stability, were briefly discussed. And then the related physical and chemical synthesis strategies were introduced in detail. Afterwards, Mn⁴⁺ doped phosphors, such as oxides, fluorides as well as glass ceramic composites, and their impact on improving the photoelectric performance of white light-emitting diodes were summarized. Finally, several challenges and perspectives for exploring novel and high-performance Mn⁴⁺ doped red phosphors will be presented.