Issue 104, 2016, Issue in Progress
From the journal:

RSC Advances

An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition†

Xiuling Chen,a   Yan Li,a   Minghu Wu,*a   Haibing Guo,a   Longqiang Jiang,a   Jian Wanga  and  Shaofa Sun*a  

* Corresponding authors

a Non-Power Nuclear Technology Collaborative Innovation Center, School of Nuclear Technology and Chemistry & Life Science, Hubei University of Science and Technology, Xianning 437100, China
E-mail: cxl828800@163.com, sunshaofa@mail.hbust.com.cn
Fax: +86-715-8338007

Abstract

A novel protocol to synthesize tert-butyl esters from benzyl cyanides and tert-butyl hydroperoxide has been successfully achieved. In the presence of tert-butyl hydroperoxide, Csp3–H bond oxidation, C–CN bond cleavage and C–O bond formation proceeded smoothly in one pot under the metal-free condition.

Graphical abstract: An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

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Article information

DOI
https://doi.org/10.1039/C6RA20966A
Article type
Communication
Submitted
20 Aug 2016
Accepted
26 Sep 2016
First published
10 Oct 2016

RSC Adv., 2016,6, 102023-102027

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An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

X. Chen, Y. Li, M. Wu, H. Guo, L. Jiang, J. Wang and S. Sun, RSC Adv., 2016, 6, 102023 DOI: 10.1039/C6RA20966A

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