A methodology that brings together sugar and steroid scaffolds linked by a selenium atom is discussed in this work. A series of 6β and 3α glycoconjugated steroids were achieved by stereoselective nucleophilic substitution of cholesterol, pregnenolone, stigmasterol and sitosterol with different seleno-pyranosides and furanosides.
R. F. Affeldt, F. P. Santos, R. S. da Silva, O. E. D. Rodrigues, L. A. Wessjohann and D. S. Lüdtke, RSC Adv., 2016, 6, 93905 DOI: 10.1039/C6RA21485A
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