Cationic nickel(II) complexes of two ring-contracted porphyrinoid ligands distantly related to the corrins were prepared by metal templated macrocyclisation. The compounds show reversible electron transfer processes and were found to be the first porphyrinoid-based catalysts for C–C cross-coupling.
R. Wicht, S. Bahnmüller, K. Brandhorst, P. Schweyen and M. Bröring, Chem. Sci., 2016, 7, 583 DOI: 10.1039/C5SC03663A
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