The dual capture of AsV and AsIII by UiO-66 and analogues

Cornelius O. Audu; Huong Giang T. Nguyen; Chih-Yi Chang; Michael J. Katz; Lily Mao; Omar K. Farha; Joseph T. Hupp; SonBinh T. Nguyen

doi:10.1039/C6SC00490C

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The dual capture of As^V and As^III by UiO-66 and analogues†

Cornelius O. Audu,^a Huong Giang T. Nguyen,^a Chih-Yi Chang,^a Michael J. Katz,^a Lily Mao,^a Omar K. Farha,*^ab Joseph T. Hupp*^a and SonBinh T. Nguyen*^a

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* Corresponding authors

^a Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA
E-mail: o-farha@northwestern.edu, j-hupp@northwestern.edu, stn@northwestern.edu

^b Department of Chemistry, Faculty of Science, King Abdulaziz University, Jedah, Saudi Arabia

Abstract

UiO-66 and analogues were successfully tailored to chemoselectively capture As^V oxyanions at the hydroxylated node and neutral As^III species with the thiolated organic linkers. More efficient and faster uptake can be achieved with increasing defect densities, increasing pore aperture sizes, and decreasing particle sizes.

This article is part of the themed collection: Global Energy Challenges: Materials and Nanotechnology

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Article information

DOI: https://doi.org/10.1039/C6SC00490C
Article type: Edge Article
Submitted: 01 Feb 2016
Accepted: 16 Jun 2016
First published: 16 Jun 2016
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry

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Chem. Sci., 2016,7, 6492-6498

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The dual capture of As^V and As^III by UiO-66 and analogues

C. O. Audu, H. G. T. Nguyen, C. Chang, M. J. Katz, L. Mao, O. K. Farha, J. T. Hupp and S. T. Nguyen, Chem. Sci., 2016, 7, 6492 DOI: 10.1039/C6SC00490C

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