Issue 7, 2016
From the journal:

Chemical Science

Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes†

Peng Cui,a   Melissa R. Hoffbauer,a   Mariya Vyushkovab  and  Vlad M. Iluc*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN, USA
E-mail: viluc@nd.edu

b Notre Dame Radiation Laboratory, University of Notre Dame, Notre Dame, IN, USA

Abstract

Heterobimetallic Pd–K carbenes featuring Pd–Ccarbene–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp2)P}tBuPdI] ([PC(sp2)P]tBu = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that can be interrupted in the presence of a donor solvent.

Graphical abstract: Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes

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Article information

DOI
https://doi.org/10.1039/C6SC00948D
Article type
Edge Article
Submitted
09 Dec 2015
Accepted
21 Mar 2016
First published
24 Mar 2016
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2016,7, 4444-4452

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Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes

P. Cui, M. R. Hoffbauer, M. Vyushkova and V. M. Iluc, Chem. Sci., 2016, 7, 4444 DOI: 10.1039/C6SC00948D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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