We have impregnated chromium(III) onto a high surface area particulate niobium oxide to make bulk oxide–oxide interfaces, identifying by a combination of X-ray photoelectron spectroscopy and diffuse reflectance the exact energy of the metal-to-metal charge transfer transition that is responsible for the visible light photocatalytic decomposition of methyl orange.
C. P. Ireland, R. G. Palgrave, S. C. Bennett, A. W. J. Smith, J. H. Clark, J. R. Darwent, J. B. Claridge, S. Poulston and M. J. Rosseinsky, J. Mater. Chem. A, 2016, 4, 12479 DOI: 10.1039/C6TA00192K
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