Issue 8, 2016
From the journal:

Journal of Materials Chemistry C

First NIR luminescent polymeric high-nuclearity Cd–Ln nanoclusters from a long-chain Schiff base ligand†

Xiaoping Yang,*ab   Shiqing Wang,ab   Lijie Zhang,ab   Shaoming Huang,*ab   Zongping Li,ab   Chengri Wang,ab   Ting Zhuab  and  Le Boab  

* Corresponding authors

a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
E-mail: xpyang@wzu.edu.cn, smhuang@wzu.edu.cn

b Zhejiang Key Laboratory of Carbon Materials, Wenzhou 325035, China

Abstract

Two classes of Cd–Ln nanoclusters [Ln6Cd22Cl14(OH)2L10(OAc)26]n (Ln = La (1) and Nd (2)), and [Yb6Cd18Cl6(OH)2L9(OAc)28] (3) were prepared using a long-chain Schiff base ligand. 1 and 2 exhibit unusual 1-D coordination polymeric structures built by 28-metal drum-like units, while 3 has a 0-D 24-metal nano-drum-like architecture. Their NIR luminescence properties were investigated.

Graphical abstract: First NIR luminescent polymeric high-nuclearity Cd–Ln nanoclusters from a long-chain Schiff base ligand

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Article information

DOI
https://doi.org/10.1039/C5TC04103A
Article type
Communication
Submitted
04 Dec 2015
Accepted
27 Jan 2016
First published
28 Jan 2016

J. Mater. Chem. C, 2016,4, 1589-1593

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First NIR luminescent polymeric high-nuclearity Cd–Ln nanoclusters from a long-chain Schiff base ligand

X. Yang, S. Wang, L. Zhang, S. Huang, Z. Li, C. Wang, T. Zhu and L. Bo, J. Mater. Chem. C, 2016, 4, 1589 DOI: 10.1039/C5TC04103A

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