Issue 1, 2017

Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

Abstract

We introduce the fully reversible folding of single chain nanoparticles (SCNPs) based on covalent hetero Diels–Alder (HDA) chemistry. A cyclopentadiene (Cp)-protected cyanodithioester (CDTE) monomer is designed and copolymerized with methyl methacrylate (MMA) via RAFT polymerization. The polymer chains are folded and subsequently unfolded by exploiting the reversible nature of the HDA reaction.

Graphical abstract: Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

Supplementary files

Article information

Article type
Communication
Submitted
11 Sep 2016
Accepted
08 Nov 2016
First published
15 Nov 2016

Chem. Commun., 2017,53, 157-160

Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

N. Wedler-Jasinski, T. Lueckerath, H. Mutlu, A. S. Goldmann, A. Walther, M. H. Stenzel and C. Barner-Kowollik, Chem. Commun., 2017, 53, 157 DOI: 10.1039/C6CC07427H

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