Transmembrane channels formed by functionalized hydrazide macrocycles are reported. The different pH values of buffer solutions have a significant effect on the K+/Cl− selectivity of the macrocycles. This unique transport behavior is mainly induced by the different distributions of charges in the tubular channels under various pH values.
P. Xin, S. Tan, Y. Wang, Y. Sun, Y. Wang, Y. Xu and C. Chen, Chem. Commun., 2017, 53, 625 DOI: 10.1039/C6CC08943G
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