Issue 11, 2017

Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols

Abstract

Palladium-catalyzed heteroannulation of [60]fullerene with phenols has been developed as a practical and efficient protocol for the one-pot synthesis of various [60]fullerene-fused benzofurans. A possible reaction mechanism is proposed to explain the formation of C60-fused benzofurans. A novel 1,2,3,16-adduct is obtained through further reaction of the electrochemically generated dianionic fullerobenzofuran with benzyl bromide.

Graphical abstract: Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols

Supplementary files

Article information

Article type
Communication
Submitted
14 Nov 2016
Accepted
13 Jan 2017
First published
13 Jan 2017

Chem. Commun., 2017,53, 1852-1855

Palladium-catalyzed synthesis of [60]fullerene-fused benzofurans via heteroannulation of phenols

F. Li, J. Wang and G. Wang, Chem. Commun., 2017, 53, 1852 DOI: 10.1039/C6CC09080J

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