nBu4NI-catalyzed oxidative cross-coupling of carbon dioxide, amines, and aryl ketones: access to O-β-oxoalkyl carbamates

Youbin Peng; Juan Liu; Chaorong Qi; Gaoqing Yuan; Jiawei Li; Huanfeng Jiang

doi:10.1039/C6CC09762F

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nBu₄NI-catalyzed oxidative cross-coupling of carbon dioxide, amines, and aryl ketones: access to O-β-oxoalkyl carbamates†

Youbin Peng,‡^a Juan Liu,‡^b Chaorong Qi,

*^a Gaoqing Yuan,*^b Jiawei Li^b and Huanfeng Jiang

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, State Key Lab of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, P. R. China
E-mail: crqi@scut.edu.cn

^b Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China
E-mail: gqyuan@scut.edu.cn

Abstract

The first nBu₄NI-catalyzed oxidative cross-coupling reaction of carbon dioxide, amines and arylketones has been successfully developed by using TBHP as the oxidant, providing an efficient, atom-economical and metal-free strategy for the synthesis of a range of O-β-oxoalkyl carbamates.

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Article information

DOI: https://doi.org/10.1039/C6CC09762F
Article type: Communication
Submitted: 08 Dec 2016
Accepted: 13 Jan 2017
First published: 13 Jan 2017

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Chem. Commun., 2017,53, 2665-2668

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nBu₄NI-catalyzed oxidative cross-coupling of carbon dioxide, amines, and aryl ketones: access to O-β-oxoalkyl carbamates

Y. Peng, J. Liu, C. Qi, G. Yuan, J. Li and H. Jiang, Chem. Commun., 2017, 53, 2665 DOI: 10.1039/C6CC09762F

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Chemical Communications