Issue 19, 2017

σ-Complexation as a strategy for designing copper-based light emitters

Abstract

Strongly emissive cuprous complexes containing a stable σ-SiH–Cu motif were prepared. These complexes serve as a proof of principle that σ-complexation can be utilized as a design principle for engineering responsive light emitting materials. Their excited state lifetimes were found to be long (∼20 μs) with high quantum yields (φ = 0.40–0.59).

Graphical abstract: σ-Complexation as a strategy for designing copper-based light emitters

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2016
Accepted
14 Feb 2017
First published
14 Feb 2017

Chem. Commun., 2017,53, 2858-2861

σ-Complexation as a strategy for designing copper-based light emitters

Y. Kim, J. Kim, J. W. Park, K. Park and Y. Lee, Chem. Commun., 2017, 53, 2858 DOI: 10.1039/C6CC10139A

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