Self-repairing metal–organic hybrid complexes for reinforcing immobilized chloroperoxidase reusability†
Abstract
A self-repairing metal–enzyme hybrid nanocatalyst with a sodium alginate (SA) coating was reported in this study. Compared with free CPO, immobilized chloroperoxidase (CPO) has similar Km and Kcat values. SA-coated CPO@Ca3(PO4)2 hybrid composites displayed robust reusability under acidic conditions, maintaining more than 85% of the catalytic activity after 12 recycles.