Issue 27, 2017

Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

Abstract

The structural and functional modeling of the active site of [NiFe]-hydrogenases has been proved to be challenging to a great extent. Herein, we report the synthesis, structures, and some properties of the NiFe-based dicarbonyl, terminal hydride, and μ-hydroxo models for the active site of [NiFe]-hydrogenases.

Graphical abstract: Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

Supplementary files

Article information

Article type
Communication
Submitted
08 Jan 2017
Accepted
06 Mar 2017
First published
06 Mar 2017

Chem. Commun., 2017,53, 3818-3821

Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

L. Song, X. Yang, M. Cao, X. Gao, B. Liu, L. Zhu and F. Jiang, Chem. Commun., 2017, 53, 3818 DOI: 10.1039/C7CC00149E

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