Issue 32, 2017

One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

Abstract

A Rh/Ni-catalyzed cascade sequence of allylamine isomerization and hydrophosphonylation to synthesize α-aminophosphonates has been disclosed. The reaction, which not only allows the generation of widespread valuable α-aminophosphonates under simple systems and mild conditions, but also enriches the process of olefin isomerization–addition both in catalytic systems and various reaction types.

Graphical abstract: One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

Supplementary files

Article information

Article type
Communication
Submitted
22 Feb 2017
Accepted
27 Mar 2017
First published
28 Mar 2017

Chem. Commun., 2017,53, 4473-4476

One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

L. Mao, C. Li, Q. Yang, M. Cheng and S. Yang, Chem. Commun., 2017, 53, 4473 DOI: 10.1039/C7CC01391D

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