Issue 37, 2017

Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

Abstract

The unique reactivity of γ-silyl allenyl esters is described. Taking advantage of the silyl group as a fluoride acceptor, these allenoates readily underwent addition to a variety of electrophiles to selectively yield products with all-carbon quaternary centers or allenoate dicarbinols. These dicarbinols were subsequently converted to novel highly substituted 6-hydro-2-pyrones.

Graphical abstract: Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

Supplementary files

Article information

Article type
Communication
Submitted
06 Mar 2017
Accepted
06 Apr 2017
First published
11 Apr 2017

Chem. Commun., 2017,53, 5125-5127

Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

S. Jana, A. Roy and S. D. Lepore, Chem. Commun., 2017, 53, 5125 DOI: 10.1039/C7CC01708A

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