Issue 42, 2017

Alkynyl sulfoxides as α-sulfinyl carbene equivalents: gold-catalysed oxidative cyclopropanation

Abstract

Alkynyl sulfoxides are shown to act as α-sulfinyl metallocarbene synthons under oxidative gold catalysis, enabling reactions that are not available from diazo-precursors. This strategy is exemplified in the synthesis of fused α-sulfinyl cyclopropanes.

Graphical abstract: Alkynyl sulfoxides as α-sulfinyl carbene equivalents: gold-catalysed oxidative cyclopropanation

Supplementary files

Article information

Article type
Communication
Submitted
24 Mar 2017
Accepted
04 May 2017
First published
04 May 2017
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 5733-5736

Alkynyl sulfoxides as α-sulfinyl carbene equivalents: gold-catalysed oxidative cyclopropanation

M. J. Barrett, G. F. Khan, P. W. Davies and R. S. Grainger, Chem. Commun., 2017, 53, 5733 DOI: 10.1039/C7CC02244A

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