An effective photo-induced β-elimination of an alcohol leading to a vinyl compound is introduced for the first time. 9-Fluorenylmethanol was irradiated in a solution using a Xe lamp and was efficiently converted to dibenzofulvene (DBF) (9-methylenefluorene) in the absence of base which is necessary in the corresponding ground-state reaction.
H. Nageh, L. Zhao, A. Nakayama, J. Hasegawa, Y. Wang and T. Nakano, Chem. Commun., 2017, 53, 8431 DOI: 10.1039/C7CC03297H
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