Issue 61, 2017
From the journal:

Chemical Communications

Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex†

Yoji Horii, ORCID logo a   Keiichi Katoh, ORCID logo *a   Brian K. Breedlovea  and  Masahiro Yamashita*abc  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan
E-mail: kkatoh@m.tohoku.ac.jp, yamasita.m@gmail.com

b WPI Research Center, Advanced Institute for Materials Research, Tohoku Universi-ty, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

c School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

A clamshell-type terbium(III)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb–Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

Graphical abstract: Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

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Article information

DOI
https://doi.org/10.1039/C7CC03553E
Article type
Communication
Submitted
08 May 2017
Accepted
10 Jul 2017
First published
10 Jul 2017

Chem. Commun., 2017,53, 8561-8564

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Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex

Y. Horii, K. Katoh, B. K. Breedlove and M. Yamashita, Chem. Commun., 2017, 53, 8561 DOI: 10.1039/C7CC03553E

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