Issue 61, 2017
From the journal:

Chemical Communications

Transforming a chemically labile [2+3] imine cage into a robust carbamate cage†

Xin-Yue Hu,a   Wen-Shan Zhang,b   Frank Rominger,a   Irene Wacker,b   Rasmus R. Schröderbc  and  Michael Mastalerz ORCID logo *ab  

* Corresponding authors

a Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
E-mail: michael.mastalerz@oci.uni-heidelberg.de

b Center for Advanced Materials, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 225, 69120 Heidelberg, Germany

c Cell Networks, Cryo Electron Microscopy, Universitätsklinikum Heidelberg, Im Neuenheimer Feld 267, 69120 Heidelberg, Germany

Abstract

The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 °C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid (pH = −1) at room temperature without decomposition.

Graphical abstract: Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

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Article information

DOI
https://doi.org/10.1039/C7CC03677A
Article type
Communication
Submitted
12 May 2017
Accepted
07 Jul 2017
First published
07 Jul 2017

Chem. Commun., 2017,53, 8616-8619

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Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

X. Hu, W. Zhang, F. Rominger, I. Wacker, R. R. Schröder and M. Mastalerz, Chem. Commun., 2017, 53, 8616 DOI: 10.1039/C7CC03677A

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