Issue 73, 2017

A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

Abstract

We report a step-by-step route to fabricate the first example of a crystalline oriented metal–organic framework thin film having an anionic inorganic pillar ligand, {Cu(4,4′-bipyridyl)2(SiF6)}. X-ray study and sorption analysis revealed its high crystallinity and porous character.

Graphical abstract: A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2017
Accepted
24 Aug 2017
First published
24 Aug 2017

Chem. Commun., 2017,53, 10112-10115

A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

Y. Watanabe, T. Haraguchi, K. Otsubo, O. Sakata, A. Fujiwara and H. Kitagawa, Chem. Commun., 2017, 53, 10112 DOI: 10.1039/C7CC03828C

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