Five-component trigonal nanoprism with six dynamic corners†
Abstract
The metallo-supramolecular trigonal prism P is based on five different components and three unlike dynamic coordination motifs: the heteroleptic phenanthroline–terpyridine complex [Zn(1)(4)]2+ (HETTAP), the heteroleptic phenanthroline–pyridine complex [Cu(2)(5A)]+ (HETPYP-I), and the pyridine → zinc(II)–porphyrin interaction.